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Stable free radical polymerization (SFRP) of styrene was carried out using bis(4-bromomethylbenzoyl)peroxide (BBMBPO)/4-hydroxyl-2,2,6,6-tetramethyl-1-piperidinyloxy (HTEMPO) or 4,4′-azobis(4 ...
Highly stable free radicals are generated by twisting π bonds around the triazine rings and by trapping in the glassy state of a polymerized TCNQ (p-TCNQ) network structure.
Chain growth polymers occur when a monomer is added to a growing chain with an active center like a free radical or ion. This method is used to produce PVC. Controlled/’living’ (or radical) ...
The step growth polymerization systems, trimesoyl chloride (TMC) reacting with m-phenylene diamine (MPD) or piperazine (PIP), are used in polyamide (PA) layer formation in thin film composite membrane ...